Can the Philicity of Radicals Be Influenced by Oriented External Electric Fields?

Autor:	Thijs Stuyver, Rik H. Verschueren, Freija De Vleeschouwer, Ruben Van Lommel, Wim M. De Borggraeve
Přispěvatelé:	Chemistry, General Chemistry, Faculty of Sciences and Bioengineering Sciences
Rok vydání:	2021
Předmět:	Dipole Chemical physics Chemistry Polarizability Electric field Radical Organic Chemistry Moment (physics) Physics::Chemical Physics Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 24:1-5
ISSN:	1523-7052 1523-7060
Popis:	Herein, the effects of an electric field on radicals are investigated for a set of model radicals with varying complexity. An electric field impacts the intrinsic philicity of a radical, as quantified by the global electrophilicity index, ω. The extent of change in philicity depends on the directionality and strength of the applied electric field and the dipole moment and polarizability of the radical.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cecd2e0493fe053c2f9d0c775a824cf3 https://doi.org/10.1021/acs.orglett.1c02935 Zobrazit plný text záznamu