Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex
| Autor: | Mehmet Ali Celik, Benedikt Wennemann, Rian D. Dewhurst, Holger Braunschweig, Stephanie Kachel |
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| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Reaction mechanism 010405 organic chemistry Ligand General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Transition metal Intramolecular force Polymer chemistry Carbene Bond cleavage Alkyl Carbon monoxide |
| Zdroj: | Angewandte Chemie International Edition. 55:5076-5080 |
| ISSN: | 1433-7851 |
| Popis: | The complete scission of the carbon-oxygen bond of carbon monoxide, while frequently observed on bulk metals and with bimetallic and cluster transition metal complexes, is unknown with monometallic systems. Reaction of a zerovalent iron bis(borylene) complex with a cyclic (alkyl)(amino)carbene revealed a highly selective intramolecular cleavage of the C-O bond of a carbonyl ligand at room temperature, leading to the formation of a highly unusual iron complex containing a base-stabilized (bora)alkylideneborane ligand. DFT investigation of the reaction mechanism suggested that the two Lewis acidic borylene boron atoms cooperate to cleave the C-O multiple bond. |
| Databáze: | OpenAIRE |
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