High-purity lignin fractions and nanospheres rich in phenolic hydroxyl and carboxyl groups isolated with alkaline deep eutectic solvent from wheat straw

Autor: Xin Yue, Terhi Suopajärvi, Shirong Sun, Otto Mankinen, Atte Mikkelson, Harri Huttunen, Sanna Komulainen, Idamaria Romakkaniemi, Juha Ahola, Ville-Veikko Telkki, Henrikki Liimatainen
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Yue, X, Suopajärvi, T, Sun, S, Mankinen, O, Mikkelson, A, Huttunen, H, Komulainen, S, Romakkaniemi, I, Ahola, J, Telkki, V V & Liimatainen, H 2022, ' High-purity lignin fractions and nanospheres rich in phenolic hydroxyl and carboxyl groups isolated with alkaline deep eutectic solvent from wheat straw ', Bioresource Technology, vol. 360, 127570 . https://doi.org/10.1016/j.biortech.2022.127570
ISSN: 1873-2976
0960-8524
DOI: 10.1016/j.biortech.2022.127570
Popis: A combined pretreatment based on alkaline deep eutectic solvent (DES) of K2CO3 and glycerol and sequential acid fractionation was developed to extract reactive lignin from wheat straw biomass. This process exhibited excellent purification performance in lignin isolation, and the lignin fractionated at low pH displayed high reactivity, having hydroxyl and carboxyl groups up to 9.60 and 2.52 mmol/g, respectively. Silica was selectively separated and removed during the precipitation stage, avoiding the “silica interference”. Moreover, DES-lignin nanospheres created by self-assembly using lignin fractions obtained by acid precipitation possessed a high zeta potential, large particle size and high content of hydrophilic groups. Overall, the findings related to the dissociation mechanism and fractionation of reactive lignin during alkaline DES pretreatment and the acid sequence precipitation are crucial for facilitating lignin valorization in high-added value products.
Databáze: OpenAIRE
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