Force–Reactivity Property of a Single Monomer Is Sufficient To Predict the Micromechanical Behavior of Its Polymer
Autor: | Sergey Akbulatov, Roman Boulatov, Yancong Tian |
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Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Journal of the American Chemical Society. 134:7620-7623 |
ISSN: | 1520-5126 0002-7863 |
Popis: | We demonstrate an accurate prediction of the micromechanical behavior of a single chain of cyclopropanated polybutadiene, which is governed by rapid isomerization of the cyclopropane moieties at ∼1.2 nN, from the force–rate correlation of this reaction measured in a small series of increasingly strained macrocycles. The data demonstrate that a single physical quantity, force, uniquely defines the dynamics across length scales from >100 to |
Databáze: | OpenAIRE |
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