Force–Reactivity Property of a Single Monomer Is Sufficient To Predict the Micromechanical Behavior of Its Polymer

Autor:	Sergey Akbulatov, Roman Boulatov, Yancong Tian
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Kinetics General Chemistry Polymer Biochemistry Chemical reaction Catalysis Cyclopropane chemistry.chemical_compound Colloid and Surface Chemistry Monomer Polybutadiene chemistry Chemical physics Physical chemistry Reactivity (chemistry) Isomerization
Zdroj:	Journal of the American Chemical Society. 134:7620-7623
ISSN:	1520-5126 0002-7863
Popis:	We demonstrate an accurate prediction of the micromechanical behavior of a single chain of cyclopropanated polybutadiene, which is governed by rapid isomerization of the cyclopropane moieties at ∼1.2 nN, from the force–rate correlation of this reaction measured in a small series of increasingly strained macrocycles. The data demonstrate that a single physical quantity, force, uniquely defines the dynamics across length scales from >100 to
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce883f87ef5b28d96b5cbb8987c48375 https://doi.org/10.1021/ja301928d Zobrazit plný text záznamu