Poly(methyl methacrylate) Films with High Concentrations of Silicon Quantum Dots for Visibly Transparent Luminescent Solar Concentrators
| Autor: | Colin Peterson, Samantha K.E. Hill, Vivian E. Ferry, Ryan Connell, Marc A. Hillmyer, Jacob T. Held, Lorraine F. Francis, Uwe Kortshagen |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Materials science Photoluminescence Nanocomposite business.industry Scanning electron microscope 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Poly(methyl methacrylate) Light scattering 0104 chemical sciences chemistry visual_art visual_art.visual_art_medium Optoelectronics General Materials Science Thin film 0210 nano-technology Luminescence business |
| Zdroj: | ACS applied materialsinterfaces. 12(4) |
| ISSN: | 1944-8252 |
| Popis: | Silicon quantum dots (Si QDs) are attractive, nontoxic luminophores for luminescent solar concentrators (LSCs). Here, we produced Si QD/poly(methyl methacrylate) (PMMA) films on glass by doctor-blading polymer solutions and achieved films with low light scattering at an order of magnitude higher Si QD weight fraction than has been achieved previously in the bulk. We suggest that the fast solidification rate of films as compared to slow bulk polymerization is an enabling factor in avoiding large agglomerates within the nanocomposites. Scanning electron microscopy confirmed that ∼100 nm or larger QD agglomerates exist in light-scattering films, and photoluminescence intensity measurements show that light scattering, if present, significantly reduces waveguiding efficiencies for LSCs. Nonscattering films fabricated in this work exhibit high ultraviolet absorption (>80%) paired with high visible transmission (>87%) and minimal visible haze (∼1%), making them well suited for semitransparent coatings for LSCs realized as solar harvesting windows. |
| Databáze: | OpenAIRE |
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