Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates
| Autor: | Cara Cesario, Marvin J. Miller, Lawrence P. Tardibono |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Oxazines
Stereoisomerism Hydroxamic Acids Medicinal chemistry Chloride Article Catalysis chemistry.chemical_compound Chlorides Organometallic Compounds medicine Molecule Organic chemistry Group 2 organometallic chemistry chemistry.chemical_classification Hydroxamic acid Molecular Structure Organic Chemistry chemistry Carbamates Oxidation-Reduction Metallocene medicine.drug |
| Zdroj: | The Journal of Organic Chemistry. 74:448-451 |
| ISSN: | 1520-6904 0022-3263 |
| DOI: | 10.1021/jo802184y |
| Popis: | Titanocene(III) chloride (Cp(2)TiCl), generated in situ, reduces N-O bonds of various substrates in good to excellent yields (72-95%). Reactions may be performed with stoichiometric Cp(2)TiCl or with catalytic Cp(2)TiCl. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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