Chiral (phosphine)-(imidazoline) PCN pincer palladium(ii ) complexes: synthesis and application in asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine
Autor: | Jun-Jian Huang, Xiao-Qi Zhang, Jing-Jing Yang, Jun-Fang Gong, Mao-Ping Song |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | Dalton Transactions. 51:8350-8367 |
ISSN: | 1477-9234 1477-9226 |
DOI: | 10.1039/d2dt01078j |
Popis: | A series of new chiral PCN pincer Pd(II) complexes 3a-l with aryl-based (phosphine)-(imidazoline) ligands were conveniently synthesized from readily available starting materials with the key step being phosphination/C-H palladation reaction. All of the new complexes were characterized by |
Databáze: | OpenAIRE |
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