Chiral (phosphine)-(imidazoline) PCN pincer palladium(ii) complexes: synthesis and application in asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine

Autor: Jun-Jian Huang, Xiao-Qi Zhang, Jing-Jing Yang, Jun-Fang Gong, Mao-Ping Song
Rok vydání: 2022
Předmět:
Zdroj: Dalton Transactions. 51:8350-8367
ISSN: 1477-9234
1477-9226
DOI: 10.1039/d2dt01078j
Popis: A series of new chiral PCN pincer Pd(II) complexes 3a-l with aryl-based (phosphine)-(imidazoline) ligands were conveniently synthesized from readily available starting materials with the key step being phosphination/C-H palladation reaction. All of the new complexes were characterized by
Databáze: OpenAIRE