Carbodiimide-Promoted Olefin Epoxidation with Aqueous Hydrogen Peroxide

Autor:	Rodgers Hicks, Patrick McGill, George Majetich, Guang-ri Sun
Rok vydání:	1998
Předmět:	Olefin fiber chemistry.chemical_compound Aqueous solution chemistry Organic Chemistry Organic chemistry Hydrogen peroxide Carbodiimide Catalysis
Zdroj:	The Journal of Organic Chemistry. 63:2564-2573
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo972026n
Popis:	Commercially available carbodiimides in hydroxylic solvents containing hydrogen peroxide with mildly basic or acidic catalysts have been found to promote the epoxidation of olefins. A commercially available 30% aqueous solution of hydrogen peroxide serves as the oxidant for this process. The presumed reactive species is a peroxyisourea generated in situ by the addition of hydrogen peroxide to the carbodiimide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cda1640a3ff6d699acf45633aa139690 https://doi.org/10.1021/jo972026n Zobrazit plný text záznamu