Third-order optical measurements of porphyrin compounds using Dark-field and D4σ-Z scan imaging techniques
Autor: | Christophe Cassagne, J.-L. Godet, Hongzhen Wang, C.B. de Araujo, Georges Boudebs |
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Přispěvatelé: | Laboratoire de Photonique d'Angers (LPHIA), Université d'Angers (UA), Laboratoire d'Ingéniérie des Systèmes Automatisés (LISA), Centre National de la Recherche Scientifique (CNRS)-Université d'Angers (UA) |
Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Materials science
Z-scan Biophysics Analytical chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Biochemistry law.invention chemistry.chemical_compound law Organic compounds Nonlinear response Z-scan technique [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics] Optical properties Linear polarization General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Laser Porphyrin Dark field microscopy Atomic and Molecular Physics and Optics 3. Good health 0104 chemical sciences chemistry Picosecond 0210 nano-technology Refractive index Cobalt |
Zdroj: | Journal of Luminescence Journal of Luminescence, Elsevier, 2018, 199, pp.319-322. ⟨10.1016/j.jlumin.2018.03.055⟩ |
ISSN: | 0022-2313 1872-7883 |
DOI: | 10.1016/j.jlumin.2018.03.055⟩ |
Popis: | The newly introduced imaging techniques D4σ and Dark-field Z-scan (DFZ-scan) are very much appropriate to measure the third-order nonlinear (NL) refractive index in the presence of high nonlinear absorption (NLA) in condensed matter. To demonstrate the large potential of both techniques we prepared and characterized porphyrins solutions in chlorobenzene and report here on the NL optical properties of 5,10,15,20-Tetraphenyl-21H,23H-porphyrin (TPP), 5,10,15,20-Tetraphenyl-21H,23H-zinc porphyrin (ZnTPP), 5,10,15,20-tetraphenyl-21H,23H-porphyrin cobalt(II) (CoTPP) and 5,10,15,20-tetrakis(4-methoxyphenyl)−21H,23H-porphyrin cobalt(II) (MCoTPP). The measurements were performed with a laser delivering low repetition rate linearly polarized single picosecond pulses at 1064 nm and 532 nm. |
Databáze: | OpenAIRE |
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