One-pot synthesis of (-)-Ambrox
| Autor: | Sun Baoguo, Liu Yongguo, Hongyu Tian, Shaoxiang Yang, Hao Yanfeng, Yanyu Lv |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Molybdenum
Multidisciplinary 010405 organic chemistry One-pot synthesis Ambergris Hydrogen Peroxide Naphthalenes 010402 general chemistry 01 natural sciences Environmentally friendly Ammonium phosphomolybdate Article 0104 chemical sciences Catalysis Ingredient chemistry.chemical_compound chemistry Yield (chemistry) Ammonium Compounds Odorants Organic chemistry Phosphoric Acids Diterpenes Hydrogen peroxide Furans |
| Zdroj: | Scientific Reports |
| ISSN: | 2045-2322 |
| Popis: | (−)-Ambrox is recognised as the prototype of all ambergris odorants. Widely used in perfumery, (−)-Ambrox is an important ingredient due to its unique scent and excellent fixative function. An environmentally friendly and practical preparation of (−)-Ambrox is still unavailable at present although a lot of attention has been paid to this hot research topic for many years. A one-pot synthesis of (−)-Ambrox was studied starting from (−)-sclareol through oxidation with hydrogen peroxide in the presence of a quaternary ammonium phosphomolybdate catalyst {[C5H5NC16H33] [H2PMo12O40]}, which gave the product a 20% overall yield. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|