UHMWPE/HDPE in-reactor blends, prepared by in situ polymerization: Synthetic aspects and characterization
| Autor: | E. Pérez, João P. Lourenço, M. R. Ribeiro, Enrique M. Vallés, Ana E. Ferreira, María L. Cerrada, Jorge Aníbal Ressia, Vicente Lorenzo, Henri Cramail |
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| Přispěvatelé: | Laboratoire Pluridisciplinaire de Recherche en Ingénierie des Systèmes, Mécanique et Energétique (PRISME), Ecole Nationale Supérieure d'Ingénieurs de Bourges (ENSI Bourges)-Université d'Orléans (UO), HYCHICO, Laboratoire de Chimie des Polymères Organiques (LCPO), Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC), Team 2 LCPO : Biopolymers & Bio-sourced Polymers, Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC), Ministerio de Economía y Competitividad (España), Fundação para a Ciência e a Tecnologia (Portugal) |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Polymers and Plastics General Chemical Engineering UHMWPE 02 engineering and technology 010402 general chemistry lcsh:Chemical technology 01 natural sciences Materials Chemistry lcsh:TA401-492 lcsh:TP1-1185 Physical and Theoretical Chemistry In situ polymerization Composite material ComputingMilieux_MISCELLANEOUS Polymer composites Organic Chemistry 021001 nanoscience & nanotechnology In-reactor blends 0104 chemical sciences Characterization (materials science) [CHIM.POLY]Chemical Sciences/Polymers lcsh:Materials of engineering and construction. Mechanics of materials High-density polyethylene 0210 nano-technology |
| Zdroj: | eXPRESS Polymer Letters, Vol 11, Iss 5, Pp 344-361 (2017) Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP Express Polymer Letters Express Polymer Letters, BME-PT Hungary, 2017, 11 (5), pp.344-361. ⟨10.3144/expresspolymlett.2017.34⟩ Digital.CSIC. Repositorio Institucional del CSIC instname |
| ISSN: | 2013-4797 1788-618X |
| Popis: | This work covers the synthesis and characterization of in-reactor Ultra-High Molecular Weight Polyethylene/ High Density Polyethylene, UHMWPE/HDPE, blends by in situ polymerization in a single reactor, through dual catalyst immobilization. These blends are synthesized combining two different catalysts (one for each targeted molar mass) co-im-mobilized in mesoporous Santa Barbara Amorphous, SBA-15, particles. First, the ethylene polymerization behavior is investigated, under different polymerization conditions. Then, studies on the thermal, mechanical and rheological characteristics of the produced in-reactor blends are presented and their performance is compared and discussed in a comprehensive way. Moreover, the effect of different filler contents on the properties exhibited by the resulting materials is investigated. Results have shown that these in-reactor UHMWPE/HDPE blends exhibit a complex thermal, mechanical and rheological behavior, which depends mainly on the proportion between the two polymer components and on the amount of SBA-15. Financial support of Fundação para a Ciência e Tecnologia, Portugal (SFRH/BD/72761/2010 and UID/QUI/00100/2013), PAUILF (Project TC 07/13), MINECO-Spain (Projects MAT2013-47972-C2-1-P and MAT2013-47972-C2-2-P) and CYTED Red Temática 311RT0417 is acknowledged |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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