Performance of a field-scale biological permeable reactive barrier for in-situ remediation of nitrate-contaminated groundwater

Autor: Hayley Devlin, Oriol Gibert, Robert M. Kalin, A. Assal, Trevor Elliot
Přispěvatelé: Universitat Politècnica de Catalunya. Departament d'Enginyeria Química, Universitat Politècnica de Catalunya. R2EM - Resource Recovery and Environmental Management
Předmět:
Zdroj: Recercat. Dipósit de la Recerca de Catalunya
instname
Gibert, O, Assal, A, Devlin, H, Elliot, T & Kalin, R M 2019, ' Performance of a field-scale biological permeable reactive barrier for in-situ remediation of nitrate-contaminated groundwater. ', Science of the Total Environment, vol. 659, pp. 211 . https://doi.org/10.1016/j.scitotenv.2018.12.340
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)
ISSN: 1879-1026
DOI: 10.1016/j.scitotenv.2018.12.340
Popis: We report the performance of a field-scale permeable reactive barrier (PRB) for the biological treatment of nitrate-contaminated groundwater. The reactive material of the PRB consisted of a mixture of gravel and mulch as a carbon source for denitrifying bacteria. The PRB was equipped with a delivery system that allowed injecting NO3− at controlled rates from the surface directly into the up-gradient layer of the PRB. This way, NO3−concentration entering the PRB was varied (from1 to 530mg/L) with the purpose of evaluating the ultimateefficiency of the PRB under different NO3− loadings. The PRB was successful at removing NO3− from groundwater at inlet concentrations up to 280 mg/L (with NO3− removal percentages ≥97%).Monitoring of groundwater at differentdepths within the PRB provided evidence that NO3− underwent denitrification preferably at the deepest part of the PRB, where more favourable reducing conditions were achieved. Among the shortcomings of the PRB were the fluctuations of groundwater fluxes caused by intense rainfalls during the study period, although they generally did not pose concern for the denitrification capacity of the PRB. Emission fluxes of gases (CO2, CH4 and N2O) from the PRB to the atmosphere were also measured. The results are finally compared with thefew others reported existing PRBs for nitrate-contaminated groundwater worldwide.
Databáze: OpenAIRE