Effective Copper and Methylene blue adsorption from industrial effluents onto activated carbons prepared from Rice husk ash and Hazelnut husks modified by Diopside: Equilibrium, Kinetics, and Experimental design
| Autor: | Farzaneh Marahel, Maryam Abrishamkar, SomayehSadat Kiamarzi, Afsaneh Maleki |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Health
Toxicology and Mutagenesis Kinetics Soil Science chemistry.chemical_element 010501 environmental sciences 01 natural sciences Husk Analytical Chemistry chemistry.chemical_compound Adsorption medicine Environmental Chemistry Waste Management and Disposal 0105 earth and related environmental sciences Water Science and Technology Diopside 010401 analytical chemistry Public Health Environmental and Occupational Health Pollution Copper Box–Behnken design 0104 chemical sciences chemistry visual_art visual_art.visual_art_medium Methylene blue Activated carbon medicine.drug Nuclear chemistry |
| Zdroj: | International Journal of Environmental Analytical Chemistry. :1-16 |
| ISSN: | 1029-0397 0306-7319 |
| DOI: | 10.1080/03067319.2021.1935911 |
| Popis: | Activated carbon from rice husk ash (AC-RH) and hazelnut husks (AC-HH) modified by Diopside (AC-RH/Diop, AC-HH/Diop) composites were synthesised and applied for the adsorption of Copper and Methylene blue from industrial effluents. Diopside was provided by the sol-gel method and activated carbon was prepared from rice husk ash and hazelnut husks. The formation of AC/Diop composites was characterised by FT-IR, FESEM, BET, and XRD analyses. Effects of pH, amount of adsorbent, and contact time at 10 mg L−1 of Copper and Methylene blue on removal percentage were studied by Box Behnken design (BBD). Optimal conditions for maximum Copper and MB by AC/Diop adsorbent (95.54% and 99.42%, respectively) were as follows: (pH = 5.45, 7.35) (adsorbent amount: 0.10, 0.45 g), and (contact time: 9.56, 13.49 min) in 20 mL of 10 mg L−1 of pollutants concentration, respectively. In addition, the adsorption kinetics, thermodynamics, and isotherms were examined. Adsorption isotherms (qmax: 184.25 and 289.51 mg g−1 for Copper and MB, respectively) and kinetics were demonstrated that the sorption processes were better described by the Langmuir and pseudo-second-order equation. |
| Databáze: | OpenAIRE |
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