Fabrication process parameters significantly affect the perovskite oxygen carriers materials (OCM) performance in chemical looping with oxygen uncoupling (CLOU)
Autor: | Mehdi Pishahang, Tjalling van der Kolk, Julian R. Tolchard, Marijke Jacobs, Anna Lind, Yngve Larring, Knuth Albertsen, Frans Snijkers, Ruth Elisabeth Stensrød, Martin Fleissner Sunding |
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Rok vydání: | 2019 |
Předmět: |
In situ XRD
Fabrication Materials science Sintering temperature Sintering 02 engineering and technology 010402 general chemistry 7. Clean energy 01 natural sciences Methane chemistry.chemical_compound Specific surface area Homogeneity (physics) TPX Physical and Theoretical Chemistry Economies of agglomeration CLOU CaMnO3 021001 nanoscience & nanotechnology Condensed Matter Physics Calcium manganite 0104 chemical sciences Chemical engineering chemistry Micropacked bed 13. Climate action CLC SEM Slurry 0210 nano-technology Chemical looping combustion |
Zdroj: | 577–589 Journal of thermal analysis and calorimetry |
ISSN: | 1588-2926 1388-6150 |
DOI: | 10.1007/s10973-019-08860-y |
Popis: | Abstract The CLOU performance of the CaTixMn0.9−xMg0.1O3 (CMTM) perovskite-type system was investigated, comparing materials produced at laboratory scale with those made at industrial ton scale. The CLOU and conversion performances were studied by a micropacked bed reactor, and crystalline phase structure and homogeneity and bulk density identified as the most important parameters affecting the performance of the OCM. Bulk density is correlated with the sintering temperature, atmosphere and time at sintering temperature, while phase homogeneity is a function of the raw materials chosen, agglomeration method and sintering procedure. Specific challenges are identified in the control of slurry homogeneity and sintering conditions in upscaled production. The degree of sintering affects the chemo-mechanical properties of the material (crushing strength and attrition index), physical properties (specific surface area), and more importantly the crystalline phases formed and their homogeneity: the quantity of “active” crystalline phases present directly determines the thermochemical conversion properties (i.e., CLOU capacity and methane conversion), oxygen transfer capacity and kinetics. Graphic abstract The fabrication parameters of the otherwise same ingredients result in quite different morphology and quality of performance in large scale. |
Databáze: | OpenAIRE |
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