Liquid Crystals Comprising π-Electronic Ions from Porphyrin–AuIII Complexes
| Autor: | Yoshifumi Sasano, Hiromitsu Maeda, Nobuhiro Yasuda, Yuya Bando, Ichiro Hisaki, Hiroki Tanaka, Yohei Haketa |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
0301 basic medicine
chemistry.chemical_classification Multidisciplinary Chemistry Stacking Supramolecular chemistry Ionic bonding 02 engineering and technology 021001 nanoscience & nanotechnology Thermotropic crystal Porphyrin Ion 03 medical and health sciences chemistry.chemical_compound Crystallography 030104 developmental biology Liquid crystal lcsh:Q lcsh:Science 0210 nano-technology Alkyl |
| Zdroj: | iScience, Vol 14, Iss, Pp 241-256 (2019) |
| ISSN: | 2589-0042 |
| Popis: | Summary: Porphyrin–AuIII complexes were found to act as π-electronic cations, which can combine with various counteranions, including π-electronic anions. Single-crystal X-ray analyses revealed the formation of assemblies with contributions of charge-by-charge and charge-segregated assemblies, depending on the geometry and electronic state of the counteranions. Porphyrin–AuIII complexes possessing aliphatic alkyl chains formed dimension-controlled ion-pairing assemblies as thermotropic liquid crystals, whose ionic components were highly organized by π–π stacking and electrostatic interactions. : Chemistry; Supramolecular Chemistry; Electronic Materials Subject Areas: Chemistry, Supramolecular Chemistry, Electronic Materials |
| Databáze: | OpenAIRE |
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