| Autor: |
Matthias Schwalbe, Samuel T. Lutta, David R. Armstrong, Allan J. B. Watson, John Reglinski, Alan R. Kennedy, Rajeev Rajasekharan-Nair, Mark D. Spicer, Anne Biernat, Annemarie Marckwordt |
| Rok vydání: |
2013 |
| Předmět: |
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| Zdroj: |
Chemistry - A European Journal. 19:13561-13568 |
| ISSN: |
0947-6539 |
| DOI: |
10.1002/chem.201300091 |
| Popis: |
Soft scorpionates have thus far been seen mainly as a family of ligands. Their chemistry is extended here to the production of novel cationic macrocycles using dihaloalkanes. By replacing the dihaloalkanes with mild oxidising agents (NO(+), I2) we obtain two unique polycyclic heterocycles. The mechanism which leads to the formation of these polycyclic heterocycles is investigated using ab initio DFT calculations. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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