Electrophilic C–H Borylation and Related Reactions of B–H Boron Cations

Autor:	Janis Jermaks, Jeff W. Kampf, Alina Borovika, Edwin Vedejs, Aleksandrs Prokofjevs
Rok vydání:	2013
Předmět:	Inorganic Chemistry Chemistry Intramolecular force Organic Chemistry Electrophile chemistry.chemical_element Physical and Theoretical Chemistry Boron Borylation Medicinal chemistry Article Catalysis
Zdroj:	Organometallics. 32:6701-6711
ISSN:	1520-6041 0276-7333
Popis:	Catalytic procedures are described for the amine-directed borylation of aliphatic and aromatic tertiary amine–boranes. Sequential double borylation is observed in cases where two or more C–H bonds are available that allow 5-center or 6-center intramolecular borylation. The HNTf2-catalyzed borylation of benzylamine–boranes provides a practical means for the synthesis of ortho-substituted arylboronic acid derivatives, suitable for Suzuki–Miyaura cross-coupling applications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cc9fe1ac563aed73875514f13e8f11e7 https://doi.org/10.1021/om400651p Zobrazit plný text záznamu