Microwave-Mediated Continuous Hydrogen Abstraction Reaction from 2-PrOH Catalyzed by Platinum on Carbon Bead
Autor: | Tomohiro Matsuo, Yoshinari Sawama, Yasunari Monguchi, Takumu Tachikawa, Wataru Teranishi, Tsuyoshi Yamada, Tomohiro Ichikawa, Hironao Sajiki |
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Jazyk: | angličtina |
Rok vydání: | 2019 |
Předmět: |
inorganic chemicals
Materials science hydrogen production Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry Hydrogen atom abstraction Heterogeneous catalysis lcsh:Chemical technology 01 natural sciences Catalysis microwave chemistry lcsh:Chemistry Microwave chemistry lcsh:TP1-1185 platinum Physical and Theoretical Chemistry Hydrogen production organic chemicals carbon heterogeneous catalyst 021001 nanoscience & nanotechnology Platinum on carbon 0104 chemical sciences chemistry lcsh:QD1-999 flow process 0210 nano-technology Platinum Microwave |
Zdroj: | Catalysts, Vol 9, Iss 8, p 655 (2019) Catalysts Volume 9 Issue 8 |
ISSN: | 2073-4344 |
Popis: | We developed a microwave-mediated continuous hydrogen production method from 2-PrOH using platinum on a spherical carbon-bead catalyst. The catalyst cartridge consisted of helical glass part, and straight glass part (helix&minus straight cartridge) was newly developed for the effective microwave heating of 2-PrOH in the presence of 5% Pt/CB. The microwave resonance was properly adjusted within 2.4&minus 2.5 GHz using the helix&minus straight cartridge with the glass resonance-adjuster tube. The reaction was conducted by the irradiation of only 10 W of single-frequency microwaves and the catalyst was used continuously for at least 13 h without any loss of catalyst activity. |
Databáze: | OpenAIRE |
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