Cobalt(II)[salen]-Catalyzed Selective Aerobic Oxidative Cross-Coupling between Electron-Rich Phenols and 2-Naphthols
| Autor: | Hagit Forckosh, Vlada Vershinin, Doron Pappo, Nagnath Yadav More, Hagai Reiss, Hadas Shalit |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Organic Chemistry chemistry.chemical_element Oxidative phosphorylation 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Coupling (electronics) Solvent chemistry.chemical_compound chemistry Polymer chemistry Oxidative coupling of methane Phenols Chemoselectivity Cobalt |
| Zdroj: | The Journal of Organic Chemistry. 84:7950-7960 |
| ISSN: | 1520-6904 0022-3263 |
| Popis: | A selectivity-driven catalyst design approach was adopted to address chemoselectivity issues in the oxidative coupling of phenols. This approach was utilized for developing a Co(II)[salen]-catalyzed aerobic oxidative cross-coupling of phenols in a recyclable 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) solvent. The waste-free conditions offer a sustainable entry to nonsymmetric biphenols via a mechanistic scheme that involves coupling of a liberated phenoxyl radical with a ligated 2-naphthoxyl radical. |
| Databáze: | OpenAIRE |
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