High-Throughput and High-Efficient Micro-solid Phase Extraction Based on Sulfonated-Polyaniline/Polyacrylonitrile Nanofiber Mats for Determination of Fluoroquinolones in Animal-Origin Foods
| Autor: | Ningge Jian, Chunmin Wang, Jiankun Cao, Qian Xu, Jian Li, Meng Zhao, Sihui Liang |
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| Rok vydání: | 2019 |
| Předmět: |
0106 biological sciences
Meat Sorbent Swine Eggs Acrylic Resins Nanofibers Food Contamination Sulfonic acid Kidney 01 natural sciences chemistry.chemical_compound Anti-Infective Agents Limit of Detection Polyaniline Animals Sample preparation Solid phase extraction Solid Phase Microextraction chemistry.chemical_classification Aniline Compounds Chromatography 010401 analytical chemistry Extraction (chemistry) Polyacrylonitrile General Chemistry High-Throughput Screening Assays 0104 chemical sciences Milk Liver chemistry Nanofiber Cattle General Agricultural and Biological Sciences Chickens Fluoroquinolones 010606 plant biology & botany |
| Zdroj: | Journal of Agricultural and Food Chemistry. 67:6892-6901 |
| ISSN: | 1520-5118 0021-8561 |
| DOI: | 10.1021/acs.jafc.9b01312 |
| Popis: | We herein describe a high-throughput 96-well plate micro-solid phase extraction sample preparation technique based on novel sulfonated-polyaniline/polyacrylonitrile nanofiber mats (sulfonated-PANI/PAN NFMs) for multiresidue detection of fluoroquinolones (FQs) in various animal-origin food samples. Through the double-modification of polyaniline and sulfonic acid, the resulting functionalized sulfonated-PANI/PAN NFMs present high extraction efficiency for FQs. Compared with the existing methods, this approach demonstrates its advantages of being suitable for more sample matrices (milk, animal muscle, liver, kidney, and egg), lower sample amount (0.5 g), lower sorbent requirement (5.0 mg), lower volume of organic solvent (0.7 mL), shorter time (0.2 min per sample), and high sensitivity (0.012-0.06 μg·kg-1). In addition, sulfonated-PANI/PAN NFMs possess excellent reusability which could be reused 10 times without an obvious decrease in extraction efficiency. Combined with ultra performance liquid chromatography-tandem mass spectrometry, the novel sample preparation technique can be expected as an efficient method for routine trace FQ residue monitoring in animal-origin food samples. |
| Databáze: | OpenAIRE |
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