A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties
| Autor: | Séverine Renaudineau, Guillaume Izzet, Anna Proust, Corentin Rinfray |
|---|---|
| Přispěvatelé: | Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Edifices PolyMétalliques (E-POM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
animal structures
chemistry.chemical_element Electron Electrochemistry Catalysis Polymer chemistry Organometallic Compounds Materials Chemistry Moiety Organic chemistry [CHIM]Chemical Sciences ComputingMilieux_MISCELLANEOUS Molybdenum Chemistry Metals and Alloys Electrochemical Techniques General Chemistry Grafting Surfaces Coatings and Films Electronic Optical and Magnetic Materials Quaternary Ammonium Compounds Covalent bond Ceramics and Composites sense organs Oxidation-Reduction |
| Zdroj: | Chemical Communications Chemical Communications, 2014, 50 (62), pp.8575--8577. ⟨10.1039/C4CC03779K⟩ Chemical Communications, Royal Society of Chemistry, 2014, 50 (62), pp.8575--8577. ⟨10.1039/C4CC03779K⟩ |
| ISSN: | 1359-7345 1364-548X |
| Popis: | A new polyoxomolybdate-based hybrid platform TBA4[PMo11O39{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid. |
| Databáze: | OpenAIRE |
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