To bend or not to bend – are heteroatom interactions within conjugated molecules effective in dictating conformation and planarity?
| Autor: | Simon J. Coles, Claire Wilson, Neil J. Findlay, Peter J. Skabara, Alexander L. Kanibolotsky, Jean-Luc Brédas, Mateusz B. Pitak, Gary Conboy, Chad Risko, Enrico Angioni, Howard J. Spencer, Veaceslav Coropceanu |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Stereochemistry
Heteroatom 02 engineering and technology Conjugated system 010402 general chemistry 01 natural sciences Materials Science(all) Molecule General Materials Science QD Electrical and Electronic Engineering Chemistry Hydrogen bond Process Chemistry and Technology 021001 nanoscience & nanotechnology Planarity testing 0104 chemical sciences Organic semiconductor Crystallography Mechanics of Materials Intramolecular force 0210 nano-technology Macromolecule |
| Zdroj: | Conboy, G, Spencer, H J, Angioni, E, Kanibolotsky, A L, Findlay, N J, Coles, S J, Wilson, C, Pitak, M B, Risko, C, Coropceanu, V, Brédas, J L & Skabara, P J 2016, ' To bend or not to bend-are heteroatom interactions within conjugated molecules effective in dictating conformation and planarity? ', Materials Horizons, vol. 3, no. 4, pp. 333-339 . https://doi.org/10.1039/c6mh00051g |
| ISSN: | 2051-6347 2051-6355 |
| Popis: | We consider the roles of heteroatoms (mainly nitrogen, the halogens and the chalcogens) in dictating the conformation of linear conjugated molecules and polymers through non-covalent intramolecular interactions. Whilst hydrogen bonding is a competitive and sometimes more influential interaction, we provide unambiguous evidence that heteroatoms are able to determine the conformation of such materials with reasonable predictability. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|