Electrogeneration of ultra-thin silica films for the functionalization of macroporous electrodes
| Autor: | Janine Gajdzik, Yémima Bon Saint Côme, Fengli Qu, Alain Walcarius, Jennifer Lenz, Rihab Nasraoui, Rolf Hempelmann, Alexander Kuhn, Mathieu Etienne |
|---|---|
| Přispěvatelé: | Laboratoire de Chimie Physique et Microbiologie pour l'Environnement (LCPME), Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC), Institut des Sciences Moléculaires (ISM), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Université Sciences et Technologies - Bordeaux 1-Université Montesquieu - Bordeaux 4-Institut de Chimie du CNRS (INC), Universität des Saarlandes [Saarbrücken] |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Condensation polymer Materials science Thin layers Biomolecule Inorganic chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences lcsh:Chemistry lcsh:Industrial electrochemistry lcsh:QD1-999 chemistry Chemical engineering [CHIM.ANAL]Chemical Sciences/Analytical chemistry Electrode Surface modification 0210 nano-technology lcsh:TP250-261 |
| Zdroj: | Electrochemistry Communications Electrochemistry Communications, Elsevier, 2011, 13 (2), pp.138-142. ⟨10.1016/j.elecom.2010.11.034⟩ Electrochemistry Communications, Vol 13, Iss 2, Pp 138-142 (2011) |
| ISSN: | 1388-2481 |
| DOI: | 10.1016/j.elecom.2010.11.034⟩ |
| Popis: | Electro-assisted generation of ultra-thin silica films can be achieved by using very dilute tetraethoxysilane (TEOS) precursors in the starting sol. The electrochemical manipulation of pH enables to catalyze polycondensation only at the electrode/solution interface, which offers the advantage of uniform deposition of thin layers onto the whole internal surfaces of macroporous gold electrodes, without any pore clogging effect. This opens promising avenues for application in various fields, as shown here for active biomolecule encapsulation. Keywords: Macroporous electrodes, Sol–gel films, Silica, Electrodeposition, Haemoglobin |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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