Postsynthetic Modification of Metal–Organic Frameworks by Vapor-Phase Grafting

Autor:	Wanbin Li, Siyi Rong, Yan Xia, Pengcheng Su, Huiyu Tang, Shizheng Chen, Miaomiao Jia
Rok vydání:	2021
Předmět:	010405 organic chemistry fungi Vapor phase 010402 general chemistry Grafting 01 natural sciences 0104 chemical sciences Inorganic Chemistry Hydrolysis chemistry.chemical_compound Acyl chloride chemistry Polymer chemistry Molecule Metal-organic framework Physical and Theoretical Chemistry Fluoride
Zdroj:	Inorganic Chemistry. 60:11745-11749
ISSN:	1520-510X 0020-1669
DOI:	10.1021/acs.inorgchem.1c00284
Popis:	A vapor-phase grafting strategy is developed for the postsynthetic modification of metal-organic frameworks (MOFs). On the basis of the Schotten-Baumann reaction between acyl chloride (-COCl) and amino (-NH2) groups and hydrolysis of -COCl, the carboxylated MOFs could be prepared through simple exposure in vaporized acyl chloride molecules and immersion in water. The modified MOFs have well-maintained crystalline structures and porosities and show substantially improved fluoride removal performance.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb75a855643c02c572cfd108c375e703 https://doi.org/10.1021/acs.inorgchem.1c00284 Zobrazit plný text záznamu