Oxidation of benzoins to benzils in the presence of porphyrin sensitizers by air and sunlight or visible light

Autor:	Roghayeh Ciyabi, Maryam Ciyabi Hashjin, Maryam Baharloui, Ghaffar Hosseini, Nava Taherizadeh
Rok vydání:	2013
Předmět:	Sunlight chemistry.chemical_compound Chemistry(all) chemistry Benzoin General Chemistry Benzil Chemoselectivity Photochemistry Acetonitrile Porphyrin Catalysis Visible spectrum
Zdroj:	Research on Chemical Intermediates. 40:2811-2822
ISSN:	1568-5675 0922-6168
DOI:	10.1007/s11164-013-1130-3
Popis:	In this work, two new aerobic routes are introduced for the oxidation of a variety of benzoins to benzils by using molecular oxygen in the presence of porphyrins as sensitizers, using white light or sunlight in acetonitrile under mild conditions. The methods have a wide range of applications, do not involve cumbersome work-up, exhibit chemoselectivity and proceed under mild reaction conditions. The resulting products are obtained in good yields in a reasonable time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb31931394937dc81f6ae789efd64abc https://doi.org/10.1007/s11164-013-1130-3 Zobrazit plný text záznamu Full text from SpringerLink