New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction
| Autor: | Jérôme Leblond, Maxime Dauchy, Gregory S. Smith, Sébastien Tilloy, Hervé Bricout, Michel Ferreira, Eric Monflier |
|---|---|
| Přispěvatelé: | Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, UCCS Équipe Catalyse Supramoléculaire, Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille-Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, University of Cape Town, Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Schiff base Aqueous solution Cyclodextrin 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry General Chemical Engineering General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Water soluble chemistry Polymer chemistry [CHIM]Chemical Sciences Hydroformylation ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Pure and Applied Chemistry Pure and Applied Chemistry, De Gruyter, 2018, 90 (5), pp.845-855. ⟨10.1515/pac-2017-1205⟩ Pure and Applied Chemistry, 2018, 90 (5), pp.845-855. ⟨10.1515/pac-2017-1205⟩ |
| ISSN: | 0033-4545 1365-3075 |
| DOI: | 10.1515/pac-2017-1205⟩ |
| Popis: | The synthesis of water-soluble rhodium(I) salicylaldiminato and salicylhydrazonic complexes has been achieved employing two preparative routes. Schiff base condensation between 6A-deoxy-6A-amino-β-CD or 6A-deoxy-6A-hydrazino-β-CD and 5-sodiosulfonato-2-hydroxybenzaldehyde (sulfonated salicylaldehyde) (1) or 5-sodiosulfonato-3-tert-butyl-2-hydroxybenzaldehyde (sulfonated t Bu-salicylaldehyde) (2) led to the formation of the corresponding imine or hydrazone ligands (3, 4, 5 and 6). Reaction of [Rh(COD)2 +BF4 −] with these new ligands in an alkaline solution formed the corresponding rhodium complexes quantitatively. These rhodium(I) complexes could also be prepared in one-pot by mixing, in stoichiometric proportions, the modified β-CDs with the sulfonated salicylaldehyde and with the rhodium precursor in an alkaline solution at room temperature. These rhodium complexes were applied as catalysts in the aqueous biphasic hydroformylation of 1-decene as a model reaction. |
| Databáze: | OpenAIRE |
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