Electrifying Sustainability on Transition Metal-Free Modes: An Eco-Friendly Approach for the Formation of C-N Bonds
| Autor: | Partha Pratim Sen, Neha Dagar, Sudipta Raha Roy |
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| Rok vydání: | 2020 |
| Předmět: |
Green chemistry
Materials science General Chemical Engineering Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrosynthesis 01 natural sciences Environmentally friendly Redox 0104 chemical sciences Catalysis General Energy Transition metal Sustainability Environmental Chemistry General Materials Science Synergistic catalysis 0210 nano-technology |
| Zdroj: | ChemSusChem. 14(5) |
| ISSN: | 1864-564X |
| Popis: | Embracing sustainable green methodologies and techniques in chemical transformations has always been in the limelight to the synthetic community. Electrosynthesis has emerged as a powerful, sustainable synthetic tool for molecular synthesis exploiting inexpensive electricity in place of sacrificial chemical oxidizing/reducing reagents. Herein, recent advances in the incorporation of transition metal-free redox mediators in electrosynthesis for the construction of C-N bonds are outlined. Furthermore, conjugation of this strategy with flow catalysis allows easy scale up of the synthesis of molecular assembly. This comprehensive Review provides an overview of metal-free mediated electro-construction of C-N bonds, focusing on the reaction mechanisms involved and its synthetic applications. |
| Databáze: | OpenAIRE |
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