Autor: |
Jef A. J. M. Vekemans, G.B.W.L. Ligthart, J Jan Meuldijk, R. H. Meijer, L.A. Hulshof |
Přispěvatelé: |
Macromolecular and Organic Chemistry, Macro-Organic Chemistry |
Jazyk: |
angličtina |
Rok vydání: |
2004 |
Předmět: |
|
Zdroj: |
Journal of Molecular Catalysis A: Chemical, 218(1), 29-40. Elsevier |
ISSN: |
1381-1169 |
DOI: |
10.1016/j.molcata.2004.04.003 |
Popis: |
RuCl 2 [ S -BINAP] catalyzed dehydrogenation of alcohols into aldehydes or ketones has been investigated. Among many H-acceptors screened, diphenylacetylene (tolane) was the most suitable judged from its smooth reduction. Electron rich and deficient analogues of tolane have been synthesized. Based on competition experiments between these H-acceptors a tentative catalytic cycle for the RuCl 2 [ S -BINAP] catalyzed dehydrogenations is proposed. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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