Lipase-catalyzed synthesis of butyl butyrate by alcoholysis in an integrated liquid-vapor system
Autor: | F. Xavier Malcata, Diman van Rossum, Ana L. Paiva |
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Přispěvatelé: | Veritati - Repositório Institucional da Universidade Católica Portuguesa |
Jazyk: | angličtina |
Rok vydání: | 2003 |
Předmět: |
Butanols
Triacylglycerol lipase Raw material Chemical reaction Catalysis Phase Transition chemistry.chemical_compound Bioreactors Bioreactor Chemical Precipitation Organic chemistry Lipase Chromatography biology Chemistry Butanol Equipment Design Enzymes Immobilized Equipment Failure Analysis Systems Integration Butyrates Alcohols biology.protein Butyl butyrate Biotechnology |
Zdroj: | Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP |
Popis: | This paper reports experimental work pertaining to alcoholysis between butanol and ethyl butanoate, catalyzed by an immobilized lipase in a liquid-vapor system where chemical reaction and physical separation are simultaneously carried out. The processing setup was tested for various compositions of the starting feedstock and operated under reduced pressure. Samples were withdrawn both from the boiler and the condenser, and they were chromatographically assayed for butyl butyrate. The integrated configuration tested is quite effective toward improvement of the final yield of the desired product. |
Databáze: | OpenAIRE |
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