CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

Autor:	Kai Altenhöner, Thomas Braun, Michael Teltewskoi, Silke Hinze, Marcel Ahijado Salomon
Rok vydání:	2009
Předmět:	Hydride chemistry.chemical_element General Medicine General Chemistry Borylation Catalysis Rhodium boryl compounds borylation chemistry fluorine rhodium Polymer chemistry Fluorine Surface modification Organic chemistry C-F activation Bond cleavage
Zdroj:	Angewandte Chemie International Edition. 48:1818-1822
ISSN:	1521-3773 1433-7851
DOI:	10.1002/anie.200805041
Popis:	Fluorinated building blocks by C-F bond cleavage: Catalytic C-F activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.
Databáze:	OpenAIRE
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