A Combined Catalyst of Pt Nanoparticles and TiO2 with Water-Tolerant Lewis Acid Sites for One-Pot Conversion of Glycerol to Lactic Acid
| Autor: | Komanoya, Tasuku, Suzuki, Ayaka, Nakajima, Kiyotaka, Kitano, Masaaki, Kamata, Keigo, Hara, Michikazu. |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Ketone catalyst platinum nanoparticle TiO2 Lewis acid pot glycerol lactate 010405 organic chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Aldehyde Catalysis 0104 chemical sciences Lactic acid Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Glycerol Organic chemistry Lewis acids and bases Physical and Theoretical Chemistry Platinum |
| Zdroj: | Chemcatchem. 8(No. 6):1094-1099 |
| Popis: | Catalytic conversion of glycerol to valuable chems. has been recognized as an attractive and challenging reaction in biorefinery. In this paper, we demonstrated that a combined catalyst of Pt nanoparticles and TiO2 worked as a highly active catalyst for the one-pot conversion of glycerol to lactic acid in water. The yield of lactic acid reached 63 % under oxygen atm. without the use of any additives such as strong bases, and the catalyst could be reused without significant loss of the catalytic performance. The mechanistic studies revealed that Pt nanoparticles on TiO2 selectively oxidized glycerol to C3 aldehyde/ketone, and Lewis acid sites on TiO2 smoothly promoted the dehydration and rehydration/rearrangement reactions of the intermediates to produce lactic acid efficiently. [on SciFinder(R)] |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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