An autocatalytic organic reaction network based on cross-catalysis
| Autor: | Benoît Limoges, François Mavré, Pan Hui, Mathieu Branca |
|---|---|
| Přispěvatelé: | Laboratoire d'Electrochimie Moléculaire (LEM (UMR_7591)), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP) |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Reactive oxygen species 010405 organic chemistry Metals and Alloys General Chemistry [CHIM.CATA]Chemical Sciences/Catalysis 010402 general chemistry Photochemistry 01 natural sciences Redox Catalysis 3. Good health 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Autocatalysis chemistry [CHIM.ANAL]Chemical Sciences/Analytical chemistry Materials Chemistry Ceramics and Composites [CHIM]Chemical Sciences |
| Zdroj: | Chemical Communications Chemical Communications, Royal Society of Chemistry, 2021, ⟨10.1039/d1cc05121k⟩ |
| ISSN: | 1359-7345 1364-548X |
| Popis: | Here we report a simple autocatalytic organic reaction network based on the redox chemistry of quinones and reactive oxygen species. Autocatalysis arises from the cross-activation between the H2O2-catalyzed deprotection of a pro-benzoquinone arylboronic ester probe and the benzoquinone-catalyzed H2O2 production through redox cyling with ascorbate in an aerated buffered solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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