Optical absorption of single-layer hexagonal boron nitride in the ultraviolet

Autor: C. D. M. Fernandes, J. C. G. Henriques, Nuno M. R. Peres, G. B. Ventura
Přispěvatelé: Universidade do Minho
Jazyk: angličtina
Předmět:
Zdroj: Journal of Physics: Condensed Matter
Repositório Científico de Acesso Aberto de Portugal
Repositório Científico de Acesso Aberto de Portugal (RCAAP)
instacron:RCAAP
ISSN: 1361-648X
0953-8984
0957-4484
2053-1583
DOI: 10.1088/1361-648x/ab47b3
Popis: In this paper we theoretically describe the absorption of hexagonal boron nitride (hBN) single layer. We develop the necessary formalism and present an efficient method for solving the Wannier equation for excitons. We give predictions for the absorption of hBN on quartz and on graphite. We compare our predictions with recently published results (Elias et al 2019 Nat. Commun. 10 2639) for a monolayer of hBN on graphite. The spontaneous radiative lifetime of excitons in hBN is also computed. We argue that the optical properties of hBN in the ultraviolet are very useful for the study of peptides and other biomolecules.
The authors would like to thank André Chaves and Bruno Amorim for reading the manuscript, making suggestions, and for discussions on the topic of the paper. NMRP acknowledges support from the European Commission through the project 'Graphene-Driven Revolutions in ICT and Beyond' (Ref. No. 785219), and the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Financing UID/FIS/04650/2019. In addition, NMRP acknowledges COMPETE2020, PORTUGAL2020, FEDER and the Portuguese Foundation for Science and Technology (FCT) through projects PTDC/FIS- NAN/3668/2013 and POCI-01-0145-FEDER-028114, and POCI-01-0145-FEDER-029265 and PTDC/NAN-OPT/29265/2017, the authors also acknowledge the funding of Fundação da Ciência e Tecnologia, of COMPETE 2020 program in the FEDER component (European Union), through the project POCI-01-0145-FEDER-02888.
Databáze: OpenAIRE