Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway
Autor: | Franck Paté, Aurélien de la Lande, Anne Harrison-Marchand, Jacques Maddaluno, Olivier Parisel, Hassan Oulyadi, Hélène Gérard |
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Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Chem. Commun.. :319-321 |
ISSN: | 1364-548X 1359-7345 |
Popis: | The exchange of Me(6)Li aggregated to a lithium amide by (7)LiCl leads to a specific isotope distribution whose microscopic origin is assigned to an edge-to-edge interaction between the R(2)NLi-MeLi aggregate and (LiCl)(2) by NMR and Car-Parrinello molecular dynamics. |
Databáze: | OpenAIRE |
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