Shuffling lithiated mixed aggregates: NMR and Car–Parrinello molecular dynamics reveal an unexpected associative pathway

Autor:	Franck Paté, Aurélien de la Lande, Anne Harrison-Marchand, Jacques Maddaluno, Olivier Parisel, Hassan Oulyadi, Hélène Gérard
Rok vydání:	2009
Předmět:	Lithium amide Shuffling Chemistry Metals and Alloys General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Molecular dynamics chemistry.chemical_compound Computational chemistry Materials Chemistry Ceramics and Composites Isotope distribution
Zdroj:	Chem. Commun.. :319-321
ISSN:	1364-548X 1359-7345
Popis:	The exchange of Me(6)Li aggregated to a lithium amide by (7)LiCl leads to a specific isotope distribution whose microscopic origin is assigned to an edge-to-edge interaction between the R(2)NLi-MeLi aggregate and (LiCl)(2) by NMR and Car-Parrinello molecular dynamics.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9d37410b68bb08630426c3791de0489 https://doi.org/10.1039/b814961e Zobrazit plný text záznamu