A Model for Radiolysis in a Flowing-Water Target during High-Intensity Proton Irradiation

Autor: Gregory Severin, Katharina Anna Domnanich
Rok vydání: 2022
Předmět:
Zdroj: ACS omega. 7(29)
ISSN: 2470-1343
Popis: At the Facility for Rare Isotope Beams (FRIB), interactions between heavy-ion beams and beam-dump water will create a wide variety of radionuclides which can be accessed by a technique known as "isotope harvesting". However, irradiation of water is always accompanied by the creation of numerous radical, ionic, and molecular radiolysis products. Some of the radiolysis products have sufficiently long lifetimes to accumulate in the irradiated water and affect the harvesting chemistry. Here we investigate the formation of hydrogen peroxide, molecular hydrogen, and molecular oxygen during a high-intensity proton irradiation of a flowing-water isotope-harvesting target and compare the experimental results to simulations. The simulations kinetically model the chemical reactions occurring in the homogeneous phase of radiolysis in flowing water and establish an "effective yield". In both the experiment and simulations, the bulk quantities of H
Databáze: OpenAIRE