Neutral Complexes of First Row Transition Metals Bearing Unbound Thiocyanates and Their Assembly on Metallic Surfaces

Autor:	Douglas Natelson, Jacob W. Ciszek, James M. Tour, Michael P. Stewart, Z. K. Keane, Lam H. Yu, Long Cheng
Rok vydání:	2006
Předmět:	Thiocyanate Stereochemistry Molecular electronics General Chemistry Electronic structure Biochemistry Catalysis Metal Crystallography chemistry.chemical_compound Colloid and Surface Chemistry chemistry Transition metal Chemisorption visual_art Monolayer visual_art.visual_art_medium Molecule
Zdroj:	Journal of the American Chemical Society. 128:3179-3189
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja055459d
Popis:	A series of transition metal coordination complexes designed to assemble on gold surfaces was synthesized, their electronic structure and transitions analyzed, and their magnetic properties studied. By taking advantage of recently developed thiocyanate assembly protocols, these molecules were then assembled onto a gold surface, without the need for an inert atmosphere, to give a loosely packed monolayer. The assembled molecules exhibit properties similar to that of the bulk molecules, indicating little change in molecular structure outside of chemisorption.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c8a884a16fbad90a1398f19e1b5fa4eb https://doi.org/10.1021/ja055459d Zobrazit plný text záznamu