A Phosphine-Based Heterotrimetallic (M = Fe, Ru, W) Homo-polymer
| Autor: | Amir Rabiee Kenaree, Joe B. Gilroy |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Ethylferrocene Organic Chemistry Alcohol Polymer 010402 general chemistry Electrochemistry 01 natural sciences 0104 chemical sciences Styrene Inorganic Chemistry chemistry.chemical_compound Chemistry chemistry Transition metal Polymerization Polymer chemistry Physical and Theoretical Chemistry Phosphine |
| Zdroj: | Chemistry Publications |
| Popis: | An organometallic homopolymer containing three different metals per repeating unit was synthesized from an air- and moisture-stable secondary phosphine bearing ethylferrocene and ethylruthenocene groups. Hydrophosphination yielded a tertiary phosphine bearing an alcohol, which was then used to introduce a polymerizable styrene group via DCC coupling. Free-radical polymerization, followed by postpolymerization coordination to photogenerated W(CO)5 units, yielded the title polymer, which showed thermal, spectroscopic, and electrochemical properties associated with each of the transition metals involved. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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