Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II)
| Autor: | Jordan M. Cox, Gage Bateman, Cassidy A. Benson, Jason B. Benedict |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
crystal structure
Stereochemistry Lead chloride 02 engineering and technology Crystal structure 010402 general chemistry 01 natural sciences Medicinal chemistry Research Communications chemistry.chemical_compound Organic inorganic General Materials Science Ammonium Crystallography biology Hydrogen bond hybrid material General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics biology.organism_classification hydrogen bonding 3. Good health 0104 chemical sciences chemistry QD901-999 Tetra Pyridinium 0210 nano-technology Hybrid material |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 11, Pp 1670-1673 (2017) |
| ISSN: | 2056-9890 |
| Popis: | The crystal structure of this hybrid organic–inorganic material exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The title compound, (C2H8N)(C7H11N2)[PbCl4], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and dimethylbenzene-1,4-diaminium. |
| Databáze: | OpenAIRE |
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