Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides

Autor: Zoltán Kupihár, Tünde Zita Illyés, Attila Bokros, János Szolomájer, Zoltán Kele, Annamária Bánfi, Lajos Kovács
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Molecules
Molecules, Vol 17, Iss 7, Pp 8351-8358 (2012)
ISSN: 1420-3049
Popis: Highly reactive glycosyl chlorides and bromides have been analysed by a routine mass spectrometric method using electrospray ionization and lithium salt adduct-forming agents in anhydrous acetonitrile solution, providing salient lithiated molecular ions [M+Li]+, [2M+Li]+ etc. The role of other adduct-forming salts has also been evaluated. The lithium salt method is useful for accurate mass determination of these highly sensitive compounds.
Databáze: OpenAIRE