Iodine complexes in inert solvents
| Autor: | G.E. McAlonie, P.A.D. de Maine, M.M. de Maine |
|---|---|
| Rok vydání: | 1962 |
| Předmět: |
Inert
Chloroform chemistry.chemical_element Iodine Atomic and Molecular Physics and Optics Standard enthalpy of formation Hexane chemistry.chemical_compound chemistry Extinction (optical mineralogy) Tetrachloride Carbon tetrachloride Physical chemistry Solvent effects Physical and Theoretical Chemistry Electronic computer Benzene Spectroscopy Equilibrium constant Nuclear chemistry |
| Zdroj: | Journal of Molecular Spectroscopy. 8:373-382 |
| ISSN: | 0022-2852 |
| DOI: | 10.1016/0022-2852(62)90038-3 |
| Popis: | Equilibrium constants, heat of formation, and molar extinction coefficients for the benzene-iodine complex, together with molar extinction coefficients for uncomplexed iodine and benzene have been calculated by means of an electronic computer from spectrophotometric data at fifteen wavelengths between 2700 A and 3500 A for the benzene-iodine-carbon tetrachloride system at 15° and 45°C. Deviations at high benzene concentrations can be qualitatively explained by the additional reactions: benzene + benzene ⇌ K 1 ( complex ) 1 ( complex ) 1 + I 2 ⇌ K 2 ( complex ) 2 with K 1 small. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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