Enhanced Solubilization of Fluoranthene by Hydroxypropyl β-Cyclodextrin Oligomer for Bioremediation
| Autor: | Eunae Cho, Jae Min Choi, Seunho Jung, Kyeong Hui Park |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
hydroxypropyl β-cyclodextrin
fluoranthene polycyclic aromatic hydrocarbons Polymers and Plastics 02 engineering and technology Nuclear Overhauser effect 010501 environmental sciences 01 natural sciences Oligomer Article lcsh:QD241-441 chemistry.chemical_compound lcsh:Organic chemistry Epichlorohydrin Solubility 0105 earth and related environmental sciences Naphthalene Fluoranthene General Chemistry 021001 nanoscience & nanotechnology chemistry Proton NMR 0210 nano-technology Two-dimensional nuclear magnetic resonance spectroscopy Nuclear chemistry |
| Zdroj: | Polymers, Vol 10, Iss 2, p 111 (2018) Polymers Polymers; Volume 10; Issue 2; Pages: 111 |
| ISSN: | 2073-4360 |
| Popis: | Fluoranthene (FT) is a polycyclic aromatic hydrocarbon (PAH), consisting of naphthalene and benzene rings connected by a five-member ring. It is widespread in the environment. The hydrophobicity of FT limits its availability for biological uptake and degradation. In this study, hydroxypropyl β-cyclodextrin oligomers (HP-β-CD-ol) were synthesized with epichlorohydrin (EP), while the solubility enhancement of FT by HP-β-CD-ol was investigated in water. The synthesized HP-β-CD-ol was characterized by MALDI-TOF mass spectrometry (MS), 1H NMR, and 13C NMR spectroscopy. The solubility of FT increased 178-fold due to the complex formation with HP-β-CD oligomers. The inclusion complexes of FT/HP-β-CD-ol were analyzed using Fourier-Transform Infrared (FT-IR), Differential Scanning Calorimetry (DSC), Scanning Electron Microscope (SEM), and Nuclear Overhauser Effect Spectroscopy Nuclear magnetic resonance (NOESY NMR) spectroscopy. On the basis of these results, HP-β-CD-ol is recommended as a potential solubilizer for the development of PAH removal systems. |
| Databáze: | OpenAIRE |
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