Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

Autor: Hiroshi Morikawa, Suguru Motokucho
Rok vydání: 2020
Předmět:
Zdroj: Chemical Communications. 56:10678-10681
ISSN: 1364-548X
1359-7345
DOI: 10.1039/d0cc04463f
Popis: We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO2 into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.
Chemical Communications, 56(73), pp.10678-10681; 2020
Databáze: OpenAIRE