Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents
| Autor: | Pierre Mangeney, Farida Mhamdi, Franz Lagasse, Alexandre Alexakis |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Chemistry Stereochemistry organic chemicals Organic Chemistry Cleavage (embryo) Aldehyde Catalysis Inorganic Chemistry Hydrolysis Reagent ddc:540 health occupations polycyclic compounds Enol ether heterocyclic compounds Physical and Theoretical Chemistry |
| Zdroj: | Tetrahedron: Asymmetry, Vol. 7, No 12 (1996) pp. 3343-3346 |
| ISSN: | 0957-4166 |
| Popis: | α,β-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral β-disubstituted aldehyde. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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