Utilization of Unsymmetric Diaryliodonium Salts in α‐Arylation of α‐Fluoroacetoacetamides

Autor:	Mohd Khalid Zaheer, Narendra Kumar Vaishanv, Kishor Mohanan, Ruchir Kant
Rok vydání:	2020
Předmět:	Metal free 010405 organic chemistry Chemistry Organic Chemistry General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences
Zdroj:	Chemistry – An Asian Journal. 15:4297-4301
ISSN:	1861-471X 1861-4728
DOI:	10.1002/asia.202001160
Popis:	The use of unsymmetric diaryliodonium salts as a versatile class of arylating agents has been demonstrated by developing a novel strategy to quickly access α-arylated α-fluoroacetoacetamides. The protocol provides a convenient metal-free method for the α-arylation of a diverse class of fluorinated acetoacetamides, and the products are obtained in good yields. The strategy, upon use of electron-deficient diaryliodonium salts as an arylating agent, provides α-fluoroacetamides through a spontaneous arylation/deacylation cascade.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c728d0647baff75dc1a04ab038016585 https://doi.org/10.1002/asia.202001160 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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