Theoretical Study of the Chemiluminescence of the Al + H2O Reaction
| Autor: | Sonia Álvarez-Barcia, Giovanni Granucci, Jesús R. Flores, Maurizio Persico |
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| Rok vydání: | 2012 |
| Předmět: |
Chemistry
Infrared aluminum water reaction Surface hopping Excimer Potential energy chemiluminescence law.invention Ab initio quantum chemistry methods law Excited state nonadiabatic dynamics simulations Molecule Physical and Theoretical Chemistry Atomic physics surface hopping atom-molecule collisions Astrophysics::Galaxy Astrophysics Chemiluminescence |
| Zdroj: | The Journal of Physical Chemistry A. 117:67-74 |
| ISSN: | 1520-5215 1089-5639 |
| DOI: | 10.1021/jp310034c |
| Popis: | We performed surface hopping simulations of Al + H2O collisions by a direct semiempirical method, reproducing the conditions of previous beam-gas experiments.(1, 2) We observed the formation of the HAlOH species, that dissociates to AlOH + H after a lifetime of about 0.6 ps. This species undergoes nonadiabatic transitions to its first excited state and is responsible for chemiluminescence in the visible range, while the Al–H2O complex emits in the infrared. The computed emission band in the visible is red-shifted with respect to the experimental one,(1, 2) because of slight inaccuracies of the potential energy surfaces. However, collisions with more water molecules and exciplex formation with excited Al(2S, 4P) atoms may also contribute to the short wavelength emission, as we show by accurate ab initio calculations. |
| Databáze: | OpenAIRE |
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