Cu-α-diimine Compounds Encapsulated in Porous Materials as Catalysts for Electrophilic Amination of Aromatic C–H Bonds

Autor:	Lisa Van Emelen, Vincent Lemmens, Carlos Marquez, Sam Van Minnebruggen, Oleg A. Usoltsev, Aram L. Bugaev, Kwinten Janssens, Ka Yan Cheung, Niels Van Velthoven, Dirk E. De Vos
Rok vydání:	2022
Předmět:	General Materials Science
Zdroj:	ACS Applied Materials & Interfaces. 14:51867-51880
ISSN:	1944-8252 1944-8244
DOI:	10.1021/acsami.2c13980
Popis:	Electrophilic amination has emerged as a more environmentally benign approach to construct arene C-N bonds. However, heterogeneous catalysts remain largely unexplored in this area, even though their use could facilitate product purification and catalyst recovery. Here we investigate strategies to heterogenize a Cu(2,2'-bipyridine) catalyst for the amination of arenes lacking a directing group with hydroxylamine
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6e65dcc4061bb1318111502906cdfdc https://doi.org/10.1021/acsami.2c13980 Zobrazit plný text záznamu