Shape-Controlled Synthesis of Silver Nanocrystals by X-ray Irradiation for Inkjet Printing
| Autor: | Weng Sing Hwang, Yu Feng Liu, Po-Wei Chen, In-Gann Chen, Ivan M. Kempson, Jenn-Ming Song, Hsien Tse Tung, Yeukuang Hwu |
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| Přispěvatelé: | Tung, Hsien-TseT, Chen, In-Gann, Kempson, Ivan, Song, J M, Liu, Yu-Feng, Chen, Po-Wei, Hwang, Weng-Sing, Hwu, Yeukuang |
| Rok vydání: | 2012 |
| Předmět: |
Silver
Materials science Macromolecular Substances Surface Properties Metal Nanoparticles Nanoparticle silver nanocrystals Nanotechnology CIBM-PC chemistry.chemical_compound Materials Testing medicine General Materials Science Particle Size Computer Peripherals shape control inkjet printing Polyvinylpyrrolidone X-Rays X-ray irradiation silver nanowires Silver nitrate chemistry Nanocrystal Chemical engineering Transmission electron microscopy Reagent Melting point Ink Selected area diffraction Crystallization medicine.drug |
| Zdroj: | ACS Applied Materials & Interfaces. 4:5930-5935 |
| ISSN: | 1944-8252 1944-8244 |
| DOI: | 10.1021/am3015718 |
| Popis: | A suite of silver (Ag) nanocrystals have been synthesized using a rapid water radiolysis approach via X-ray irradiation. Various shapes including spheroidal, prism, rod, and multifaceted nanoparticles can be produced by varying the initial concentration of polyvinylpyrrolidone (PVP) relative to silver nitrate (AgNO3). UV-visible spectroscopy and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED) have been used to characterize these Ag products. At an optimized reagent ratio, a mixture of high-aspect-ratio rods (tunable to similar to 50) and spheroidal particles result. Such a mixture is proven to have highly beneficial melting point and dispersive properties suited to inkjet printing of conductive Ag lines. The resistivity of the printed lines decreases to 77.7 mu Omega and 33.1 mu Omega after heating to 200 and 350 degrees C. Refereed/Peer-reviewed |
| Databáze: | OpenAIRE |
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