Structure and rheology of the defect-gel states of pure and particle-dispersed lyotropic lamellar phases
| Autor: | Sriram Ramaswamy, Vinay Kumaran, Prabhu R. Nott, Suneel, Geetha Basappa, Rout Deeleep Kumar, Vijay M. Naik |
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| Jazyk: | angličtina |
| Rok vydání: | 1999 |
| Předmět: |
Materials science
Rheometry Physics FOS: Physical sciences Dynamic mechanical analysis Condensed Matter - Soft Condensed Matter Chemical Engineering Condensed Matter Physics Electronic Optical and Magnetic Materials Condensed Matter::Soft Condensed Matter Rheology Phase (matter) Lyotropic Soft Condensed Matter (cond-mat.soft) Particle Lamellar structure Elasticity (economics) Composite material |
| Zdroj: | IndraStra Global. |
| ISSN: | 2381-3652 |
| Popis: | We present important new results from light-microscopy and rheometry on a moderately concentrated lyotropic smectic, with and without particulate additives. Shear-treatment aligns the phase rapidly, except for a striking network of oily-streak defects, which anneals out much more slowly. If spherical particles several microns in diameter are dispersed in the lamellar medium, part of the defect network persists under shear-treatment, its nodes anchored on the particles. The sample as prepared has substantial storage and loss moduli, both of which decrease steadily under shear-treatment. Adding particles enhances the moduli and retards their decay under shear. The data for the frequency-dependent storage modulus after various durations of shear-treatment can be scaled to collapse onto a single curve. The elasticity and dissipation in these samples thus arises mainly from the defect network, not directly from the smectic elasticity and hydrodynamics. Comment: 19 pages inclusive of 12 PostScript figures, uses revtex, psfrag and epsfig. Revised version, accepted for publication in Euro. Phys. J. B, with improved images of defect structure and theoretical estimates of network elasticity and scaling |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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