A Family of Dioxo−Molybdenum(VI) Complexes of N2X Heteroscorpionate Ligands of Relevance to Molybdoenzymes
| Autor: | Simon Einwächter, Brian S. Hammes, Carl J. Carrano, Bal S. Chohan, Justin T. Hoffman |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Models
Molecular Molybdenum Molecular Structure Stereochemistry Chemistry Atom (order theory) chemistry.chemical_element Ligands Enzymes Inorganic Chemistry Oxygen atom Metalloproteins Electrochemistry Organometallic Compounds Thermodynamics Reactivity (chemistry) Physical and Theoretical Chemistry Isostructural Oxidation-Reduction |
| Zdroj: | Inorganic Chemistry. 43:7800-7806 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic049130p |
| Popis: | Four new Mo(VI)-dioxo complexes of a family of N2X heteroscorpionate ligands are reported which, together with data already available for (TpR)-, provide a unique example of a comprehensive set of isostructural, isoelectronic complexes differing only in one biologically relevant donor atom. A study of these complexes allows for a direct comparison of structural, spectroscopic, and oxygen atom transfer reactivity properties of the Mo(VI)-dioxo center (of relevance to various families of molybdoenzymes) as a function of donor atom identity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|